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ZINC

ZINC
ZINC structure
CAS No.
7440-66-6
Chemical Name:
ZINC
Synonyms
Zn;ls2;ls6;Zink;65ZN;ZINC;Jasad;Pasco;zinc6a;CLAYZIC
CBNumber:
CB0700715
Molecular Formula:
Zn
Formula Weight:
65.39
MOL File:
7440-66-6.mol

ZINC Properties

Melting point:
420 °C(lit.)
Boiling point:
907 °C(lit.)
Density 
7.14 g/mL at 25 °C
vapor pressure 
1 mm Hg ( 487 °C)
Flash point:
1 °F
storage temp. 
2-8°C
solubility 
H2O: soluble
form 
wire
color 
Silvery-gray
Specific Gravity
7.14
Resistivity
5.8 μΩ-cm, 20°C
Water Solubility 
Soluble in water.
Sensitive 
Air & Moisture Sensitive
Merck 
14,10132
Stability:
Stable. Incompatible with amines, cadmium, sulfur, chlorinated solvents, strong acids, strong bases. Air and moisture sensitive. Zinc powder is very flammable.
InChIKey
HCHKCACWOHOZIP-UHFFFAOYSA-N
CAS DataBase Reference
7440-66-6(CAS DataBase Reference)
NIST Chemistry Reference
Zinc(7440-66-6)
EPA Substance Registry System
Zinc(7440-66-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  N,F,Xi,Xn
Risk Statements  52/53-50/53-17-15-36/37/38-51/53-36/37-22-19-40-11
Safety Statements  26-61-60-46-43-36-36/37-16
RIDADR  UN 3264 8/PG 3
WGK Germany  3
RTECS  ZH1400000
3
Autoignition Temperature 460 °C
TSCA  Yes
HS Code  7904 00 00
HazardClass  8
PackingGroup  III
Hazardous Substances Data 7440-66-6(Hazardous Substances Data)
Toxicity Zinc is an essential nutrient and is not regarded as toxic. However, the metal fumes, its oxide fumes, and chloride fumes can produce adverse inhalation effects. (See Zinc Oxide and Zinc Chloride, Toxicity) Ingestion of soluble salts can cause nausea.
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger P210, P222, P280, P302+P334,P370+P378, P422
H251 Self-heating; may catch fire Self-heating substances and mixtures Category 1 Danger
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232 Handle under inert gas. Protect from moisture.
P391 Collect spillage. Hazardous to the aquatic environment
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P407 Maintain air gap between stacks/pallets.
P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding … oC/…oF.
P422 Store contents under …
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
1
0 1
Health   0 Poses no health hazard, no precautions necessary and would offer no hazard beyond that of ordinary combustible materials
Flammability   1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
Instability   1 Normally stable, but can become unstable at elevated temperatures and pressures (e.g. propene)
Special  

(NFPA, 2010)

ZINC price More Price(85)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 209988 Zinc dust, <10 μm, ≥98% 7440-66-6 1kg $79.5 2018-11-13 Buy
Sigma-Aldrich 209988 Zinc dust, <10 μm, ≥98% 7440-66-6 5kg $242 2018-11-13 Buy
Alfa Aesar 041655 Zinc sputtering target, 50.8mm (2.0in) dia x 3.18mm (0.125in) thick 99.99% (metals basis) 7440-66-6 1each $237 2018-11-20 Buy
Alfa Aesar 041656 Zinc sputtering target, 50.8mm (2.0in) dia x 6.35mm (0.250in) thick 99.99% (metals basis) 7440-66-6 1each $316 2018-11-20 Buy
Strem Chemicals 30-0040 Zinc foil (99.9+%) 7440-66-6 5pcs $213 2018-11-13 Buy

ZINC Chemical Properties,Uses,Production

Chemical Properties

silver or blueish-white foil or powder

Chemical Properties

Zinc is one of the most common elements in the earth’s crust. Metal zinc was fi rst produced in India and China during the middle ages. Industrially important compounds of zinc are zinc chloride (ZnCl2), zinc oxide (ZnO), zinc stearate (Zn(C16H35O2)2), and zinc sulfi de (Sphalerite, ZnS) found in hazardous waste sites. It is found in air, soil, and water, and is present in all foods. Pure zinc is a bluish-white shiny metal. Zinc has many commercial uses as coatings to prevent rust, in dry-cell batteries, and mixed with other metals to make alloys like brass and bronze. Zinc combines with other elements to form zinc compounds. Zinc compounds are widely used in industry to make paint, rubber, dye, wood preservatives, and ointments.

Chemical Properties

Zinc is a soft silvery colored metal; the dust is odorless and gray.

Physical properties

Bluish-white lustrous metal; brittle at room temperature; malleable between 100 to 150°C; hexagonal close-packed structure; density 7.14 g/cm3; melts at 419.6°C; vaporizes at 907°C; vapor pressure 1 torr at 487°C, 5 torr at 558°C and 60 torr at 700°C; good conductor of electricity, electrical resistivity 5.46 microhm-cm at 0°C and 6.01 microhm-cm at 25°C; surface tension 768 dynes/cm at 600°C; viscosity 3.17 and 2.24 centipoise at 450 and 600°C, respectively; diamagnetic; magnetic susceptibility 0.139x10–6 cgs units in polycrystalline form; thermal neutron absorption cross-section 1.1 barns.

Physical properties

Zinc is a whitish metal with a bluish hue. As an electropositive metal, it readily gives up itstwo outer electrons located in the N shell as it combines with nonmetal elements. Zinc foilwill ignite in moist air, and zinc shavings and powder react violently with acids. Zinc’s meltingpoint is 419.58°C, its boiling point is 907°C, and its density is 7.14 g/cm3.Note: Zinc is not always included as one of the metals in the first series of the transitionelements, but it is the first element in group 12 (IIB).

Isotopes

There are 38 isotopes of zinc, ranging in atomic weights from Zn-54 to Zn-83.Just four of these are stable, and those four, plus one naturally radioactive isotope (Zn-70) that has a very long half-life (5×10+14 years), make up the element’s existence onEarth. Their proportional contributions to the natural existence of zinc on Earth are assuch: Zn-64 = 48.63%, Zn-66 = 27.90%, Zn-67 = 4.10%, Zn- 68 = 18.75%, and Zn-70 = 0.62%. All the other isotopes are radioactive and artificially produced.

Origin of Name

Although ancients used zinc compounds, the name “zinc” is assumed to be derived from the German word zinn, which was related to tin.

Occurrence

Zinc is the 24th most abundant on Earth, which means it makes up only about 0.007%of the Earth’s crust. Even so, humans have found many uses for it over the past thousands ofyears.It is not found in its pure metallic form in nature but is refined from the mineral (compound) zinc sulfide (ZnSO4) known as the ores sphalerite and zincblende. It is also recoveredfrom minerals and ores known as willemite, hydrozincite, smithsonite, wurtzite, zincite, andFranklinite. Zinc ores are found in Canada, Mexico, Australia, and Belgium, as well as in theUnited States. Valuable grades of zinc ores are mined in Colorado and New Jersey.

Characteristics

Zinc is malleable and can be machined, rolled, die-cast, molded into various forms similarto plastic molding, and formed into rods, tubing, wires, and sheets. It is not magnetic, butit does resist corrosion by forming a hard oxide coating that prevents it from reacting anyfurther with air. When used to coat iron, it protects iron by a process called “galvanic protection,” also known as “sacrificial protection.” This protective characteristic occurs because theair will react with the zinc metal coating, which is a more electropositive (reactive) metal thanis the coated iron or steel, which is less electropositive than zinc. In other words, the zinc isoxidized instead of the underlying metal. (See the section under “Common Uses of Zinc” formore on galvanization.

History

Centuries before zinc was recognized as a distinct element, zinc ores were used for making brass. Tubal-Cain, seven generations from Adam, is mentioned as being an “instructor in every artificer in brass and iron.” An alloy containing 87% zinc has been found in prehistoric ruins in Transylvania. Metallic zinc was produced in the 13th century A.D. in India by reducing calamine with organic substances such as wool. The metal was rediscovered in Europe by Marggraf in 1746, who showed that it could be obtained by reducing calamine with charcoal. The principal ores of zinc are sphalerite or blende (sulfide), smithsonite (carbonate), calamine (silicate), and franklinite (zinc, manganese, iron oxide). Canada, Japan, Belgium, Germany, and the Netherlands are suppliers of zinc ores. Zinc is also mined in Alaska, Tennessee, Missouri, and elsewhere in the U.S. Zinc can be obtained by roasting its ores to form the oxide and by reduction of the oxide with coal or carbon, with subsequent distillation of the metal. Other methods of extraction are possible. Naturally occurring zinc contains five stable isotopes. Twenty-five other unstable isotopes and isomers are recognized. Zinc is a bluish-white, lustrous metal. It is brittle at ordinary temperatures but malleable at 100 to 150°C. It is a fair conductor of electricity, and burns in air at high red heat with evolution of white clouds of the oxide. The metal is employed to form numerous alloys with other metals. Brass, nickel silver, typewriter metal, commercial bronze, spring brass, German silver, soft solder, and aluminum solder are some of the more important alloys. Large quantities of zinc are used to produce die castings, used extensively by the automotive, electrical, and hardware industries. An alloy called Prestal?, consisting of 78% zinc and 22% aluminum, is reported to be almost as strong as steel but as easy to mold as plastic. It is said to be so plastic that it can be molded into form by relatively inexpensive die casts made of ceramics and cement. It exhibits superplasticity. Zinc is also extensively used to galvanize other metals such as iron to prevent corrosion. Neither zinc nor zirconium is ferromagnetic; but ZrZn2 exhibits ferromagnetism at temperatures below 35 K. Zinc oxide is a unique and very useful material to modern civilization. It is widely used in the manufacture of paints, rubber products, cosmetics, pharmaceuticals, floor coverings, plastics, printing inks, soap, storage batteries, textiles, electrical equipment, and other products. It has unusual electrical, thermal, optical, and solid- state properties that have not yet been fully investigated. Lithopone, a mixture of zinc sulfide and barium sulfate, is an important pigment. Zinc sulfide is used in making luminous dials, X-ray and TV screens, and fluorescent lights. The chloride and chromate are also important compounds. Zinc is an essential element in the growth of human beings and animals. Tests show that zinc-deficient animals require 50% more food to gain the same weight as an animal supplied with sufficient zinc. Zinc is not considered to be toxic, but when freshly formed ZnO is inhaled a disorder known as the oxide shakes or zinc chills sometimes occurs. It is recommended that where zinc oxide is encountered good ventilation be provided. The commercial price of zinc in January 2002 was roughly 40¢/lb ($90 kg). Zinc metal with a purity of 99.9999% is priced at about $5/g.

Uses

zinc is described as an oligo element, trace element, or micro nutrient. Zinc is believed to accelerate wound healing. It is also considered an anti-oxidant, offering protection against uV radiation. It appears to favor the sulfur uptake in sulfurated amino acids and facilitates the incorporation of cysteine, an amino acid, into the skin. It also has a synergistic effect with vitamins A and e. Zinc is a component of more than 70 metal enzymes. It promotes collagen synthesis in the dermis and keratinization of the corneum layer. Zinc is useful for acne treatments because it lowers sebaceous secretion, and is also used in the treatment of psoriasis.

Uses

Galvanizing sheet iron; as ingredient of alloys such as bronze, brass, Babbitt metal, German silver, and special alloys for die-casting; as a protective coating for other metals to prevent corrosion; for electrical apparatus, especially dry cell batteries, household utensils, castings, printing plates, building materials, railroad car linings, automotive equipment; as reducing agent in organic chemistry; for deoxidizing bronze; extracting gold by the cyanide process, purifying fats for soaps; bleaching bone glue; manufacture of sodium hydrosulfite; insulin zinc salts; as reagent in analytical chemistry, e.g., in the Marsh and Gutzeit test for arsenic; as a reducer in the determination of iron. It is a nutritional trace element.

Uses

Zinc is another earliest known metal. Use of its alloy, brass, dates back to prehistoric times. The metal was produced in India in the 13th century by reducing calamine (a silicate mineral of zinc) with wool. Marggraf produced the metal in 1746 by reducing calamine with charcoal. The element took its name from the German word zink meaning “of obscure origin.” Lohneyes first used this name in 1697. Zinc occurs in nature, widely distributed. The principal ores are sphalerite (and wurtzite) known as zinc blende, ZnS; gahnite, ZnAl2O4; calamine; smithsonite, ZnCO3; franklinite, ZnFe2O4; and zincite, ZnO. Abundance in earth’s crust is about 70 mg/kg and average concentration in sea water is about 10 µg/L. Some important applications of zinc include galvanizing steel; to produce die castings; as a chemical additive in rubber and paints; in dry cells; in making electrodes; and as a reducing agent. Steel is galvanized by a thin coating of zinc to protect it from corrosion. Such galvanized steel is used in buildings, cars, and appliances. High-purity zinc is alloyed with aluminum at varying compositions, along with small amounts of copper and magnesium, to produce die castings. Such die castings are used extensively in automotive, hardware, and electrical industries. Zinc forms numerous alloys including brass, nickel silver, German silver, commercial bronze, soft solder, aluminum solder, and spring brass. The laboratory use of zinc includes preparating hydrogen gas and as a reducing agent in a number of chemical reactions. Zinc salts have numerous uses (See under specific compounds). Zinc is an essential nutrient element required for growth of animals.

Uses

Today about one-third of all the zinc metal is used for the process known as galvanization.This process provides a protective coating of zinc on other metals. A thin layer of zinc oxidizes inair, thus providing a galvanic corrosion protection to the iron or steel item that it coats. Severalprocesses are used to galvanize other metals. One is the “hot dip” method wherein the outersurface of the item to be galvanized is “pickled” and then immersed into a molten zinc bath. A second method plates iron or steel items with a thin coat of zinc by electrolysis. Because of zinc’srelatively high reactivity, it does not need to be actually coated onto the surface of some metalsto protect them. For instance, a small disk made of zinc is sometimes attached to the rudderor other parts of an oceangoing ship. This zinc metal is “sacrificed,” as it oxidizes and corrodes,while the iron rudder does not corrode and remains protected by the galvanic process.Zinc is used with copper and other metals to produce alloys of brass, bronze, and specialdie-casting alloys (e.g., copper, aluminum, nickel, and titanium).It is used in dry cell (batteries), in fungicides (to kill fungi and molds), for roofing, and inwrapping wires for protection.Zinc is an important trace element required for all healthy plants and animals. Zinc isfound in proteins, such as meats, fish, eggs, and milk. About 10 to 15 milligrams of zinc isrequired per day, and it may be taken as a dietary supplement. Zinc helps the blood in ourbodies move the waste gas—carbon dioxide—to the lungs and helps prevent macular degeneration (loss of vision).

Uses

(Zn) A metallic element that functions as a nutrient and dietary supplement. It is believed to be necessary for nucleic acid metabolism, protein synthesis, and cell growth. Sources of include zinc acetate, carbonate, chloride, citrate, gluconate, oxide, stearate, and sulfate. The gluconate form is used in lozenges. The sulfate form exists as prisms, needles, or powder. It has a solubility of 1 g in 0.6 ml of water and is found in frozen egg substitutes.

Uses

Zinc is a constituent of many common alloys,including brass, bronze, Babbit metal, andGerman Silver. It is used to make householdutensils, castings, printing plates, buildingmaterials, electrical apparatus, dry-cell batteriesand many zinc salts. It is also used to galvanize sheet iron, bleaching bone glue andas a reducing agent in many organic reactions.

Uses

Zinc is an ingredient in alloys such as brass,bronze, and German silver. It is used as a protectivecoating to prevent corrosion of othermetals, for galvanizing sheet iron, in goldextraction, in utensils, in dry cell batteries, andas a reducing agent in organic synthesis.

Uses

This bluish white metallic element is found in sphalerite ore that is roasted to give an oxide that is reduced with carbon to make zinc vapor, which is condensed. Elemental zinc foil was occasionally used to decolorize old collodion rich in iodine. The zinc halides were used primarily in collodion emulsions.

Definition

A bluish-white transition metal occurring naturally as the sulfide (zinc blende) and carbonate (smithsonite). It is extracted by roasting the ore in air and then reducing the oxide to the metal using carbon. Zinc is used to galvanize iron, in alloys (e.g. brass), and in dry batteries. It reacts with acids and alkalis but only corrodes on the surface in air. Zinc ions are identified in solution by forming white precipitates with sodium hydroxide or ammonia solution, both precipitates being soluble in excess reagent. Symbol: Zn; m.p. 419.58°C; b.p. 907°C; r.d. 7.133 (20°C); p.n. 30; r.a.m. 65.39.

Definition

zinc: Symbol Zn. A blue-white metallicelement; a.n. 30; r.a.m. 65.38; r.d.7.1; m.p. 419.88°C; b.p. 907°C. It occursin sphalerite (or zinc blende,ZnS), which is found associated withthe lead sulphide, and in smithsonite(ZnCO3). Ores are roasted to give theoxide and this is reduced with carbon(coke) at high temperature, the zincvapour being condensed. Alternatively,the oxide is dissolved in sulphuricacid and the zinc obtained byelectrolysis. There are five stable isotopes(mass numbers 64, 66, 67, 68,and 70) and six radioactive isotopesare known. The metal is used in galvanizingand in a number of alloys(brass, bronze, etc.). Chemically it is areactive metal, combining with oxygenand other nonmetals and reactingwith dilute acids to releasehydrogen. It also dissolves in alkalis to give zincates. Most of its compoundscontain the Zn2+ ion.

Reactions

Zinc exhibits a valence of +2 in all its compounds. It also is a highly electropositive metal. It replaces less electropositive metals from their aqueous salt solutions or melts. For example, a zinc metal bar put into Cu2+ solution acquires a brown-black crust of copper metal deposited on it. At the same time the blue color of the solution fades. Zinc reduces Cu2+ ions to copper metal. The overall reaction is:

Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s) This spontaneous reaction was used first in 1830 to make a voltaic cell. The metal is attacked by mineral acids. Reactions with sulfuric and hydrochloric acids produce hydrogen. With nitric acid, no hydrogen is evolved but the pentavalent nitrogen is reduced to nitrogen at lower valence states. Zinc is attacked by moist air at room temperature. Dry air has no action at ambient temperatures but the metal combines with dry oxygen rapidly above 225°C. Zinc reacts with carbon dioxide in the presence of moisture at ordinary temperatures forming a hydrated basic carbonate. The metal, on heating with dry halogen gases, yields zinc halides. However, in the presence of moisture the reaction occurs rapidly at ambient temperatures. The metal dissolves in hot solutions of caustic alkalis to form zincates and evolves hydrogen:

Zn + 2NaOH → Na2ZnO2 + H2

General Description

A grayish powder. Insoluble in water. May produce toxic zinc oxide fumes when heated to very high temperatures or when burned. Used in paints, bleaches and to make other chemicals.

Air & Water Reactions

Can evolve gaseous hydrogen in contact with water or damp air. The heat of the reaction may be sufficient to ignite the hydrogen produced [Haz. Chem. Data 1966. p. 171]. Flammable. May form an explosive mixture with air [Hawley].

Reactivity Profile

ZINC METAL is a reducing agent. Reacts violently with oxidants causing fire and explosion hazards [Handling Chemicals Safely 1980. p. 966]. In the presence of carbon, the combination of chlorine trifluoride with zinc results in a violent reaction [Mellor 2, Supp. 1: 1956]. Sodium peroxide oxidizes zinc with incandescence [Mellor 2:490-93 1946-47]. Zinc powder or dust in contact with acids forms hydrogen. The heat generated by the reaction is sufficient to ignite the hydrogen evolved [Lab. Govt. Chemist 1965]. A mixture of powdered zinc and an oxidizing agent such as potassium chlorate or powdered sulfur can be exploded by percussion. Zinc burns in moist chlorine. A mixture of zinc and carbon disulfide reacts with incandescence. Zinc powder reacts explosively when heated with manganese chloride. The reaction between zinc and selenium or tellurium is accompanied by incandescence [Mellor 4:476-480 1946-47]. When zinc and ammonium nitrate are mixed and wetted with a minimum of water, a violent reaction occurs with evolution of steam and zinc oxide. When hydrazine mononitrate is heated in contact with zinc a flaming decomposition occurs at temperatures a little above its melting point. Hydroxylamine is reduced when heated with ZINC, unpredictably ZINC may either ignite and burn or explode [Mellor 8 1946-47].

Hazard

As mentioned, zinc dust and powder are very explosive. When zinc shavings are placedin acid or strong alkaline solutions, hydrogen gas is produced, which may explode. Many ofzinc’s compounds are toxic if inhaled or ingested.
A deficiency of zinc in humans will retard growth, both physically and mentally, andcontribute to anemia. It is present in many foods, particularly proteins (meat). A balanceddiet provides an adequate amount of zinc. Not more than 50 milligrams per day of dietaryzinc supplement should be taken, given that high levels of zinc in the body are toxic. Humanbodies contain about two grams of zinc. A deficiency of zinc can cause a lack of taste and candelay growth as well as cause retardation in children.
Zinc intoxication can occur both from inhaling zinc fumes and particles, mainly in industrialprocesses, and from orally ingesting an excess of zinc in dietary supplements. Zinc intoxicationcan cause stomach pains, vomiting, and bleeding. Excess zinc also can cause prematurebirth in pregnant women.

Health Hazard

Zinc is another essential metal, a cofactorto many metalloenzymes. Its deficiencycan induce effects on liver, nervous system,eye, skin and testis. Excessive intakeof this metal, however, may produce adverseeffects. The toxicity of the metal from ingestionis relatively low as it is readily excreted.Chronic exposure to the fume, however, maylead to “metal fume fever,” which couldprobably be attributed to the bivalent zincion, Zn2+. Although the metal in its zerovalentstate exhibits little inhalation toxicity,in its oxidation state or as oxide it canpresent a serious health hazard. Inhalationof Zn2+ or metal oxide fume can producea sweet metallic taste, cough, chills, fever,dry throat, nausea, vomiting, blurred vision,ache, weakness, and other symptoms. Thenontoxic fume of the metal is susceptible tooxidize in the air in the presence of moistureand in contact with many other substancesin air. The metal powder or its dust is a skinirritant.

Health Hazard

Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution.

Health Hazard

Zinc and its compounds are relatively non-toxic, but very large doses can produce an acute gastroenteritis characterized by nausea, vomiting, and diarrhea. The recommended dietary allowance (RDA) for zinc is 15 mg/day for men, 12 mg/day for women, 10 mg/day for children, and 5 mg/day for infants. Insuffi cient zinc in the diet can result in a loss of appetite, a decreased sense of taste and smell, slow wound healing and skin sores, or a damaged immune system. Pregnant women with low zinc intake have babies with growth retardation. Exposure to zinc in excess, however, can also be damaging to health. Harmful health effects generally begin at levels from 10–15 times the RDA (in the 100–250 mg/day range). Eating large amounts of zinc, even for a short time, can cause stomach cramps, nausea, and vomiting. Chronic exposures to zinc chloride fumes cause irritation, pulmonary edema, bronchopneumonia, pulmonary fi brosis, and cyanosis. It also causes anemia, pancreas damage, and lower levels of high-density lipoprotein cholesterol. Breathing large amounts of zinc (as dust or fumes) can cause a specifi c short-term disease, called metal fume fever, including disturbances in the adrenal secretion. Information on the possible toxicological effects following prolonged period of exposures to high concentrations of zinc is not known.

Fire Hazard

Produce flammable gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard.

Agricultural Uses

Zinc (Zn) is a bluish-white metal belonging to the 12th Group of the Periodic Table. It occurs naturally as sphalerite, smithsonite, hemimorphite and wurzite, and is extracted by roasting the oxide and reducing with carbon. It is used for galvanizing,

Industrial uses

Hot-dipped or galvanized zinc coatings havebeen popular for many years for protecting ferrousproducts because of their ideal combinationof high corrosion protection and low cost.Their corrosion protection stems from threeimportant factors:zinc has a slower rate ofcorrosion than iron,zinc corrosion productsare white and nonstaining, and zinc affordselectrolytic protection to iron.
The amount of protection against corrosiondepends largely upon coating weight — theheavier the coating, the longer the life of the base metal. For example, a coating 0.04 mmthick is expected to have a life of 25 years inrural atmospheres, whereas a 0.88-mm coatingwill last 50 years. The life of zinc coatings maybe five to ten times greater in rural atmospheresthan in industrial atmospheres containing sulfurand acid gases. Nevertheless, the coatings arestill popular for industrial use because of theirlow cost.Hot dipping is particularly valuable for zinccoating parts that cannot conveniently be madeof galvanized sheet. Thus, it is quite popular forstructural parts, castings, bolts, nuts, nails, polelinehardware, heater and condenser coils,windlasses, and many other products.

Safety Profile

Human systemic effects by ingestion: cough, dyspnea, and sweating. A human skin irritant. Pure zinc powder, dust, and fume are relatively nontoxic to humans by inhalation. The dfficulty arises from oxidation of zinc fumes immedately prior to inhalation or presence of impurities such as Cd, Sb, As, Pb. Inhalation may cause sweet taste, throat dryness, cough, weakness, generalized aches, chills, fever, nausea, vomiting. Flammable in the form of dust when exposed to heat or flame. May i p t e spontaneously in air when dry. Explosive in the form of dust when reacted with acids. Incompatible with NH4NO3, BaO2, Ba(NO3)2, Cd, CS2, chlorates, Cl2, ClF3, CrO3, (ethyl acetoacetate + tribromoneo- pentyl alcohol), F2, hydrazine mononitrate, hydroxylamine, Pb(N3)2, (Mg + Ba(NO3)2 + BaO2), MnCl2, HNO3, performic acid, KCLO3, KNO3, K2O2, Se, NaClO3, Na2O2, S, Te, H2O2 (NH4)2S, As2O3, CS2, CaCl2, NaOH, chlorinated rubber, catalytic metals, halocarbons, o-nitroanisole, nitrobenzene, nonmetals, oxidants, paint primer base, pentacarbonyliron, transition metal halides, seleninyl bromide. To fight fire, use special mixtures of dry chemical. When heated to decomposition it emits toxic fumes of ZnO. See also ZINC COMPOUNDS.

Potential Exposure

Zinc is used most commonly as a protective coating of other metals. In addition, it is used in alloys, such as bronze and brass, for electrical apparatus in many common goods; and in organic chemical extractions and reductions. Zinc chloride is a primary ingredient in smoke bombs used by military for screening purposes, crowd dispersal and occasionally in firefighting exercises by both military and civilian communities. In pharmaceuticals, salts of zinc are used as solubilizing agents in many drugs, including insulin.

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Shipping

UN1436 Zinc powder or zinc dust, Hazard Class: 4.3; Labels: 4.3-Dangerous when wet material, 4.2-Spontaneously combustible material.

Purification Methods

Commercial zinc dust (1.2kg) is stirred with 2% HCl (3L) for 1minute, then the acid is removed by filtration, and washed in a 4L beaker with a 3L portion of 2% HCl, three 1L portions of distilled water, two 2L portions of 95% EtOH, and finally with 2L of absolute Et2O. (The wash solutions were removed each time by filtration.) The material is then dried thoroughly, and if necessary, any lumps are broken up in a mortar. [Wagenknecht & Juza Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol II p 1067 1965.]

Incompatibilities

Dust is pyrophoric and may self-ignite in air. A strong reducing agent. Violent reaction with oxidizers, chromic anhydride; manganese chloride; chlorates, chlorine and magnesium. Reacts with water and reacts violently with acids, alkali hydroxides; and bases forming highly flammable hydrogen gas. Reacts violently with sulfur, halogenated hydrocarbons and many other substances, causing fire and explosion hazard.

Waste Disposal

Zinc powder should be reclaimed. Unsalvageable waste may be buried in an approved landfill. Leachate should be monitored for zinc content.

ZINC Preparation Products And Raw materials

Raw materials

Preparation Products


ZINC Suppliers

Global( 245)Suppliers
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Mainchem Co., Ltd.
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
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Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) [email protected] China 40395 62

View Lastest Price from ZINC manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-17 ZINC
7440-66-6
US $1.00 / kg 1kg 99% 100KG career henan chemical co

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