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ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Siloxane >1,1,3,3-Tetramethyldisiloxane

1,1,3,3-Tetramethyldisiloxane

1,1,3,3-Tetramethyldisiloxane Suppliers list
Company Name: Jiangxi New jiayi New Materials Co., Ltd.
Tel: 15988280056
Email: [email protected]; [email protected]
Products Intro: Product Name:1,1,3,3- Tetramethyldisiloxane; 1,1,3,3-tetramethyl-disiloxan
CAS:3277-26-7
Purity:99% Package:20kg pails and 140kg drums Remarks:1,1,3,3- Tetramethyldisiloxane; 1,1,3,3-tetramethyl-disiloxan; 1,3-Dihydrotetramethyldisiloxane;Bis(dimethylsilyl) oxide;bis(dimethylsilyl)oxide
Company Name: Kingfirst chemical (nanjing) co.,ltd
Tel: 86-25-84522992
Email: [email protected]
Products Intro: Product Name:1,1,3,3- Tetramethyldisiloxane
CAS:3277-26-7
Company Name: Hebei Guanlang Biotechnology Co., Ltd.
Tel: +86-0311-66562153 whatsapp +8615203118427
Email: [email protected]
Products Intro: Product Name:1,1,3,3-Tetramethyldisiloxane
CAS:3277-26-7
Purity:99% Package:1KG;10USD
Company Name: Hangzhou Bayee Chemical Co., Ltd.
Tel: 0086-571-86990109; 0086-18605816692
Email: [email protected]
Products Intro: Product Name:1,1,3,3-Tetramethyldisiloxane
CAS:3277-26-7
Purity:99.0%min Package:1KG/900.00; Remarks:High purity
Company Name: Capot Chemical Co.,Ltd.
Tel: +86 (0)571-855 867 18
Email: [email protected]
Products Intro: Product Name:1,1,3,3-Tetramethyldisiloxane
CAS:3277-26-7
Purity:98%(Min.HPLC) Package:100g;1kg;5kg,10kg,25kg,50kg

Lastest Price from 1,1,3,3-Tetramethyldisiloxane manufacturers

1,1,3,3-Tetramethyldisiloxane Basic information
Product Name:1,1,3,3-Tetramethyldisiloxane
Synonyms:TETRAMETHYLDISILOXANE;(CH3)2HSiOSiH(CH3)2;1,1,3,3-tetramethyl-disiloxan;1,3-Dihydrotetramethyldisiloxane;Bis(dimethylsilyl) oxide;bis(dimethylsilyl)oxide;CT2030;Dimethylsilyl ether
CAS:3277-26-7
MF:C4H14OSi2
MW:134.32
EINECS:221-906-4
Product Categories:-;Silicone serier;Industrial/Fine Chemicals;Reduction;Si (Classes of Silicon Compounds);Tetramethyldisiloxane;Si-H Compounds;Siloxanes;Si-O Compounds;Synthetic Organic Chemistry;Hydrogensilanes Hydrogensiloxanes;Reducing Agents;Organometallic Reagents;Organosilicon
Mol File:3277-26-7.mol
1,1,3,3-Tetramethyldisiloxane Structure
1,1,3,3-Tetramethyldisiloxane Chemical Properties
Melting point <-78°C
Boiling point 70-71 °C(lit.)
density 0.76 g/mL at 25 °C(lit.)
vapor pressure 250 hPa (20 °C)
refractive index n20/D 1.370(lit.)
Fp 14 °F
storage temp. 2-8°C
form liquid
color colorless
Specific Gravity0.757
explosive limit0.8-62.9%(V)
Water Solubility DECOMPOSES
Sensitive Moisture Sensitive
BRN 1733364
InChIKeyNVYQDQZEMGUESH-UHFFFAOYSA-N
CAS DataBase Reference3277-26-7(CAS DataBase Reference)
NIST Chemistry Reference((CH3)2SiH)2O(3277-26-7)
EPA Substance Registry SystemDisiloxane, 1,1,3,3-tetramethyl-(3277-26-7)
Safety Information
Hazard Codes F
Risk Statements 11-36/37/38-16
Safety Statements 16-26-36-9-33-29
RIDADR UN 2924 3/PG 2
WGK Germany 3
RTECS JN1000000
10-21
Autoignition Temperature240 °C
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29310095
MSDS Information
ProviderLanguage
1,1,3,3-Tetramethyldisiloxane English
ACROS English
SigmaAldrich English
ALFA English
1,1,3,3-Tetramethyldisiloxane Usage And Synthesis
Description1,1,3,3-Tetramethyldisiloxane is soluble in many organic solvents, such as aromatic hydrocarbon and petroleum hydrocarbons, and so on. This product is a kind of widely used organic silicon intermediates, and usually be used as organic silicon blocking agent. Due to containing reactive Si-H groups in the molecular structure, it can be used in the synthesis of copolymer macromolecule by hydrosilylation. The synthesis of copolymer macromolecule can be made into a series of reactive silicone oil.
Chemical PropertiesColorless or yellowish transparent liquid
Uses1. Synthesis of polysiloxane containing faculties end groups.
2. Can be used for the preparation of high performance organic silicone surfactants.
3. Applicable to the production of many products, such as addition silicon rubber, silica gel, Hydrogenpolysiloxane and plastic, resin modifier, dendrite polymer special additives, etc.
Uses1, 1, 3, 3-Tetramethyldisiloxane is a kind of siloxane derivative, and can be used as a monomer for the preparation of silicone polymers or silicone resins. It is used as an intermediate for preparing other organosilicon compounds. It is also used in non-aqueous polymer preparation as well as a laboratory reagent. In organic synthesis, it finds an application as an effective reducing agent in platinum-catalyzed reduction of carboxamides to amines as well as in the Au/TiO2-catalyzed hydrosilylation of carbonyl compounds (e.g., reduction of aldehydes or ketones) relative to monohydrosilanes. It can also enable a direct bromination of carboxylic acids in the presence of indium bromide (InBr3) as catalyst.
Purification Methods1,Possible impurity is 1,1,5,5-tetramethyl-3-trimethylsiloxytrisiloxane b 154-155o/733mm. Fractionate it, collect fractions boiling below 80o and re-fractionate it. Its purity can be analysed by alkaline hydrolysis and measuring the volume of H2 liberated followed by gravimetric estimation of silica in the hydrolysate. It is unchanged when stored in glass containers in the absence of moisture for 2-3 weeks. Small amounts of H2 are liberated on long storage. Care should be taken when opening a container due to pressure developed. [Speier et al. J Am Chem Soc 79 974 1958, Emeléus & Smythe J Chem Soc 609 1958, IR: Kriegsmann Z Anorg Chem 299 78 1959, Beilstein 4 IV 3991.]
Referenceshttps://www.alfa.com/en/catalog/B23697/
http://www.organic-chemistry.org/chemicals/reductions/tetramethyldisiloxane-TMDSO.shtm
https://www.infona.pl/resource/bwmeta1.element.elsevier-722236cc-df38-37aa-bbed-029ec07d525f
1,1,3,3-Tetramethyldisiloxane Preparation Products And Raw materials
Tag:1,1,3,3-Tetramethyldisiloxane(3277-26-7) Related Product Information
3-(2-Aminoethylamino)propyl-dimethoxymethylsilane 3-Aminopropyltriethoxysilane SILANE COUPLING AGENT BIS (ACETOXYBUTYL) TETRAMETHYLDISILOXANE 1,3-BIS(IODOMETHYL)TETRAMETHYLDISILOXANE BIS(TRIFLUOROPROPYL)TETRAMETHYLDISILOXANE BIS(CARBOXYPROPYL)TETRAMETHYLDISILOXANE METHACRYLOXYPROPYL TERMINATED POLYDIMETHYLSILOXANE 1,3-BIS(CHLOROMETHYL)-1,1,3,3-TETRAMETHYLDISILOXANE,1,3-BIS(CHLOROMETHYL)TETRAMETHYLDISILOXANE,BIS(CHLOROMETHYL)TETRAMETHYLDISILOXANE,1,3-Di-(chloromethyl)-tetramethyldisiloxan BIS[(BICYCLOHEPTENYL)ETHYL]TETRAMETHYLDISILOXANE BIS(DICHLOROMETHYL)TETRAMETHYLDISILOXANE,1,3-BIS(DICHLOROMETHYL)TETRAMETHYLDISILOXANE,1,3-BIS(DICHLOROMETHYL)-1,1,3,3-TETRAMETHYLDISILOXANE 1,3-Bis(bromomethyl)-1,1,3,3-tetramethyldisiloxane,BIS(BROMOMETHYL)TETRAMETHYLDISILOXANE 1,3-BIS(HYDROXYBUTYL)TETRAMETHYLDISILOXANE 1,3-DIVINYLTETRAMETHYLDISILOXANE = 1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE 1,3-BIS(CARBOMETHOXY)TETRAMETHYLDISILOXANE BIS(3-CHLOROPROPYL)TETRAMETHYLDISILOXANE,1,3-BIS(CHLOROPROPYL)TETRAMETHYLDISILOXANE 1-ALLYL-1,1,3,3-TETRAMETHYLDISILOXANE BIS(M-ALLYLPHENYLDIMETHYLSILYLOCTYL)TETRAMETHYLDISILOXANE

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